In June 2015, when the cameras on NASA’s approaching New Horizons spacecraft first spotted the large reddish polar region on Pluto’s largest moon, Charon, mission scientists knew two things: they’d never seen anything like it elsewhere in our solar system, and they couldn’t wait to get the story behind it. Scientists discovered that Charon’s polar coloring comes from Pluto itself – as methane gas that escapes from Pluto’s atmosphere and becomes “trapped” by the moon’s gravity and freezes to the cold, icy surface at Charon’s pole.
http://www.nasa.gov/feature/pluto-paints-its-largest-moon-red